Cyclic iron tetra N-heterocyclic carbenes are a family of organometallic complexes that are unique in their steric and electronic tunability. This is because the iron is linked directly to four carbon atoms in its equator which belong to the highly tunable N-heterocyclic carbene (NHC) ligand system. The ligands that are attached to the iron center can be modified to change the neighboring chemical environment of the iron. This allows researchers to tune the reactivity and the electronic configuration of the iron and study reaction intermediates that are relevant to important chemical conversions or can lead to new catalyst designs.
"}{"fact":"The term \u201cpuss\u201d is the root of the principal word for \u201ccat\u201d in the Romanian term pisica and the root of secondary words in Lithuanian (puz) and Low German\u00a0puus. Some scholars suggest that \u201cpuss\u201d could be imitative of the hissing sound used to get a cat\u2019s attention. As a slang word for the female pudenda, it could be associated with the connotation of a cat being soft, warm, and fuzzy.","length":387}
{"slip": { "id": 181, "advice": "Rule number 1: Try not to die. Rule number 2: Don't be a dick."}}
{"fact":"A 2007 Gallup poll revealed that both men and women were equally likely to own a cat.","length":85}
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{"type":"standard","title":"God of Gamblers III: Back to Shanghai","displaytitle":"God of Gamblers III: Back to Shanghai","namespace":{"id":0,"text":""},"wikibase_item":"Q4088982","titles":{"canonical":"God_of_Gamblers_III:_Back_to_Shanghai","normalized":"God of Gamblers III: Back to Shanghai","display":"God of Gamblers III: Back to Shanghai"},"pageid":5185489,"thumbnail":{"source":"https://upload.wikimedia.org/wikipedia/en/a/a7/God_of_Gamblers_III_Back_to_Shanghai_poster.jpg","width":257,"height":388},"originalimage":{"source":"https://upload.wikimedia.org/wikipedia/en/a/a7/God_of_Gamblers_III_Back_to_Shanghai_poster.jpg","width":257,"height":388},"lang":"en","dir":"ltr","revision":"1286938368","tid":"86942d33-1fd0-11f0-9bb7-df5af4b2b94d","timestamp":"2025-04-22T23:21:32Z","description":"1991 Hong Kong film","description_source":"local","content_urls":{"desktop":{"page":"https://en.wikipedia.org/wiki/God_of_Gamblers_III%3A_Back_to_Shanghai","revisions":"https://en.wikipedia.org/wiki/God_of_Gamblers_III%3A_Back_to_Shanghai?action=history","edit":"https://en.wikipedia.org/wiki/God_of_Gamblers_III%3A_Back_to_Shanghai?action=edit","talk":"https://en.wikipedia.org/wiki/Talk:God_of_Gamblers_III%3A_Back_to_Shanghai"},"mobile":{"page":"https://en.m.wikipedia.org/wiki/God_of_Gamblers_III%3A_Back_to_Shanghai","revisions":"https://en.m.wikipedia.org/wiki/Special:History/God_of_Gamblers_III%3A_Back_to_Shanghai","edit":"https://en.m.wikipedia.org/wiki/God_of_Gamblers_III%3A_Back_to_Shanghai?action=edit","talk":"https://en.m.wikipedia.org/wiki/Talk:God_of_Gamblers_III%3A_Back_to_Shanghai"}},"extract":"God of Gamblers III: Back to Shanghai is a 1991 Hong Kong comedy film, a sequel to God of Gamblers II (1990). The film is directed by Wong Jing, and stars Stephen Chow and Ng Man-tat. God of Gamblers III continues the story of the Saint of Gamblers (Chow), and does not feature the Knight of Gamblers or the God of Gamblers. The story is about Chow accidentally going back in time to Shanghai in 1937, as he tries to figure out how to return to Hong Kong in 1991.","extract_html":"
God of Gamblers III: Back to Shanghai is a 1991 Hong Kong comedy film, a sequel to God of Gamblers II (1990). The film is directed by Wong Jing, and stars